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Abstract Pulsed EPR experiments have proven to be an important tool for measuring EPR spectra, kinetics and relaxation rates of free radicals and triplet molecules. The EPR frequencies and selection rules from CW-EPR spectra also govern pulsed EPR-experiments, but pulsed excitation provides much greater control over spin dynamics and allows clean separation and measurement of many properties of the spin system. Most pulsed EPR measurements of triplet molecules have been made in the selective pulse limit where only one EPR transition of a molecule is excited by microwave pulses and its EPR spectroscopy behaves like that of a radical with spin ofmore » « less
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Chen, Hanjiao; Maryasov, Alexander G.; Rogozhnikova, Olga Yu.; Trukhin, Dmitry V.; Tormyshev, Victor M.; Bowman, Michael K. (, Phys. Chem. Chem. Phys.)
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